According to government figures, 99,939 people sought asylum in the UK in 2022.
In contrast the number making initial applications for Germany was over 243,000, while France saw 156,000 and Spain around 117,000, according to Eurostat.
Austria also had more asylum seekers at 112,000 - although Italy's total of 84,300 was lower than Britain.
In total, EU27 countries had more than 965,000 asylum seekers in 2022, up from 677,000 in 2017.
The figures do not cover most arrivals from Ukraine, with the UK and EU countries operating separate visa routes.